Original Article
  • Effect of Mechanical and Toughening Characteristics of Epoxy/Carbon Fiber Composite by Polyamide 6 Particles, CTBN Addition Technology
  • Sung-Youl Bae*, Kyo-Moon Lee*,**, Sanjay Kumar**, Ji-Hun Seok*,***, Jae-Wan Choi*,****, Woo-Hyuk Son*,*****, Yun-Hae Kim**†

  • * Aero Transport Material Center, Korea Institute of Ceramic Engineering & Technology
    ** Department of Ocean Advanced Materials Convergence Engineering, Korea Maritime and Ocean University
    *** Major of Mechanical Engineering, Korea Pusan National University
    **** Graduate School of Convergence Science, Pusan National University
    ***** Major of Mechanical Engineering, Korea Gyeongsang National University

  • Polyamide 6 입자 및 CTBN 첨가 기술에 따른 에폭시/탄소섬유 복합재의 강인화 효과 및 기계적 특성
  • 배성열*· 이교문*,**· Sanjay Kumar**· 석지훈*,***· 최재완*,****· 손우혁*,*****· 김윤해**†

  • This article is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/4.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

References
  • 1. Gabr, M.H., Abd Elrahman, M., Okubo, K., and Fujii, T., “A Study on Mechanical Properties of Bacterial Cellulose/epoxy Reinforced by Plain Woven Carbon Fiber Modified with Liquid Rubber,” Composites Part A: Applied Science and Manufacturing, Vol. 41, No. 9, 2010, pp. 1263-1271.
  •  
  • 2. Hayes, B.S., and Seferis, J.C., “Toughened Carbon Fiber Prepregs Using Combined Liquid and Preformed Rubber Materials,” Polymer Engineering & Science, Vol. 41, No. 2, 2001, pp. 170-177.
  •  
  • 3. Monteserín, C., Blanco, M., Murillo, N., Pérez-Márquez, A., Maudes, J., Gayoso, J., and Vilas, J.L., “Effect of Different Types of Electrospun Polyamide 6 Nanofibres on the Mechanical Properties of Carbon Fibre/epoxy Composites,” Polymers, Vol. 10, No. 11, 2018, pp. 1190.
  •  
  • 4. Kinloch, A.J., and Taylor, A.C., “The Toughening of Cyanate-ester Polymers Part I Physical Modification Using Particles, Fibres and Woven-mats,” Journal of Materials Science, Vol. 37, 2002, pp. 433-460.
  •  
  • 5. Hsieh, T.H., Kinloch, A.J., Masania, K., Sohn Lee, J., Taylor, A.C., and Sprenger, S., “The Toughness of Epoxy Polymers and Fibre Composites Modified with Rubber Microparticles and Silica Nanoparticles,” Journal of Materials Science, Vol. 45, 2010, pp. 1193-1210.
  •  
  • 6. Kim, S.H., and Park, S.J., “Effect of Graphitic Nanofibers on Interfacial Adhesion and Fracture Toughness of Carbon Fibers-Reinforced Epoxy Composites,” Composites Research, Vol. 34, No. 2, 2021, pp. 82-87.
  •  
  • 7. Wu, J., Li, C., Hailatihan, B., Mi, L., Baheti, Y., and Yan, Y., “Effect of the Addition of Thermoplastic Resin and Composite on Mechanical and Thermal Properties of Epoxy Resin,” Polymers, Vol. 14, No. 6, 2022, pp. 1087.
  •  
  • 8. Gu, H., Ma, C., Liang, C., Meng, X., Gu, J., and Guo, Z., “A Low Loading of Grafted Thermoplastic Polystyrene Strengthens and Toughens Transparent Epoxy Composites,” Journal of Materials Chemistry C, Vol. 5, No. 17, 2017, pp. 4275-4285.
  •  
  • 9. Chaudhary, S., Parthasarathy, S., Mangla, V., Kumar, D., and Roy, P.K., “Toughening of Epoxy with Preformed Polyethylene Thermoplastic Filler,” Polymer-Plastics Technology and Engineering, Vol. 54, No. 9, 2015, pp. 907-915.
  •  
  • 10. Zhou, Y., Xiao, Y., Wu, Q., and Xue, Y., “A Multi-state Progressive Cohesive Law for the Prediction of Unstable Propagation and Arrest of Mode-I Delamination Cracks in Composite Laminates,” Engineering Fracture Mechanics, Vol. 248, 2021, pp. 107-684.
  •  
  • 11. Chaudhary, S., Parthasarathy, S., Mangla, V., Kumar, D., and Roy, P.K., “Toughening of Epoxy with Preformed Polyethylene Thermoplastic Filler,” Polymer-Plastics Technology and Engineering, Vol. 54, No. 9, 2015, pp. 907-915.
  •  
  • 12. Akbari, R., Beheshty, M.H., and Shervin, M., “Toughening of Dicyandiamide-cured DGEBA-based Epoxy Resins by CTBN Liquid Rubber,” Iranian Polymer Journal, Vol. 22, 2013, pp. 313-324.
  •  
  • 13. Xie, Z., Tang, X., Yang, P., Sun, M., Yang, K., and Huang, Q., “Carboxyl-terminated Butadiene-acrylonitrile-modified Carbon Paper for Use of Gas Diffusion Layer in PEM Fuel Cells,” International Journal of Hydrogen Energy, Vol. 40, No. 41, 2015, pp. 14345-14352.
  •  
  • 14. Ramos, V.D., Da Costa, H.M., Soares, V.L., and Nascimento, R.S., “Modification of Epoxy Resin: A Comparison of Different Types of Elastomer,” Polymer Testing, Vol. 24, No. 3, 2015, pp. 387-394.
  •  
  • 15. Bian, X., Tuo, R., Yang, W., Zhang, Y., Xie, Q., Zha, J., and He, S., “Mechanical, Thermal, and Electrical Properties of BN–Epoxy Composites Modified with Carboxyl-terminated Butadiene Nitrile Liquid Rubber,” Polymers, Vol. 11, No. 10, 2019, pp. 1548.
  •  
  • 16. Shukla, S.K., and Srivastava, D., “Blends of Modified Epoxy resin and Carboxyl‐terminated Polybutadiene,” Journal of Applied Polymer Science, Vol. 100, No. 3, 2006, pp. 1802-1808.
  •  
  • 17. Ma, S.Q., Liu, W.Q., Hu, C.H., and Wang, Z.F., “Modification of Epoxy Resins with Polyether-g-polysiloxanes,” Iranian Polymer Journal, Vol. 19, No. 3, 2010, pp. 185-196.
  •  
  • 18. Devi, A., and Srivastava, D., “Studies on the Blends of Cardanol-based Epoxidized Novolac Type Phenolic Resin and Carboxyl-terminated Polybutadiene (CTPB), I,” Materials Science and Engineering: A, Vol. 458, No. 1-2, 2007, pp. 336-347.
  •  
  • 19. Mathew, V.S., Sinturel, C., George, S.C., and Thomas, S., “Epoxy Resin/liquid Natural Rubber System: Secondary Phase Separation and Its Impact on Mechanical Properties,” Journal of Materials Science, Vol. 45, 2010, pp. 1769-1781.
  •  
  • 20. Shaker, K., Nawab, Y., and Saouab, A., “Influence of Silica Fillers on Failure Modes of Glass/vinyl Ester Composites under Different Mechanical Loadings,” Engineering Fracture Mechanics, Vol. 218, 2019, pp. 106605.
  •  
  • 21. Girodet, C., Espuche, E., Sautereau, H., Chabert, B., Ganga, R., and Valot, E., “Influence of the Addition of Thermoplastic Preformed Particles on the Properties of an Epoxy/anhydride Network,” Journal of Materials Science, Vol. 31, 1996, pp. 2997-3002.
  •  
  • 22. Park, H.N., Lee, H.S., and Huh, M., “Effect of Various Sizing Agents on the Properties of Nylon6/Carbon Fiber Composites Prepared by Reactive Process,” Composites Research, Vol. 31, No. 6, 2018, pp. 299-303.
  •  
  • 23. Mansouri, K., Djebaili, H., and Brioua, M., “Mechanical Behavior of Particle Reinforced Thermoplastic Matrix Composites Using Finite Element Modeling”, Journal of Nano- and Electronic Physics, Vol. 12, No 5, 2020, pp. 05004.
  •  
  • 24. Thirunavukkarasu, N., Gunasekaran, H.B., Peng, S., Laroui, A., Wu, L., and Weng, Z., “Study on the Interface Toughening of Particle/fibre Reinforced Epoxy Composites with Molecularly Designed Core–shell Particles and Various Interface 3D Models,” Materials & Design, Vol. 225, pp. 111510.
  •  

This Article

Correspondence to

  • Yun-Hae Kim
  • Department of Ocean Advanced Materials Convergence Engineering, Korea Maritime and Ocean University

  • E-mail: yunheak@kmou.ac.kr